[Co(5-NH2-bdc)(bpy)
| 【Numbering】BK2021013016 | 【CAS】1177410-74-0 | ||
| 【Item No.】 | 【specification】 | ||
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Other name: Co(AIP)(BPY)
CAS: 1177410-74-0
Structure information
Unit molecular formula C26H20N4O10Co2.H2O Unit molecular weight 684.34
Coordination metal Co ligand 5-aminoisophthalic acid (CAS: 99-31-0) Bipyridine (CAS: 553-26-4)
Aperture 8A Pore volume /
Specific surface almost no nitrogen adsorption
Analog structure
Product traits
Product morphology Purple Crystals Purple Crystals
Particle size
>5*30um particles
stability
1) Co(AIP)(BPY) is relatively stable in the air and can be stable for several weeks, and stable for several days in aqueous and weak alkaline solutions
2) Thermal decomposition temperature is about 400℃
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the oven at 150 degrees (vacuum) for 6 hours before use
Other features
NA
Application field
1) Microporous MOF material can be used for the separation of ethylene and ethane
Characterization map
references
1) Hu Y, Zhang W, Zhang X, Wang Z, Li Y, Bai J. Inorg Chem Commun. 2009,12(2),166-168, DOI: 10.1016/j.inoche.2008.12.005; Two corrugated 2D bilayer (63)(658) topological coordination polymers: synthesis, structure, and water-induced reversible transformation.
2) M. Zeng, S. Hu, Q. Chen, G. Xie, Q. Shuai, S. Gao, LY Tang, Inorg. Chem. 2009, 48, 7070–7079, DOI: 10.1021/ic801794e; Apical Ligand Substitution , Shape Recognition, Vapor-Adsorption Phenomenon, and Microcalorimetry for a Pillared Bilayer Porous Framework That Shrinks or Expands in Crystal-to-Crystal Manners upon Change in the Cobalt(II) Coordination Environment
3) H. Wu, Y. Yuan, Y. Chen, F. Xu, D. Lv, Y. Wu, Z. Li, Q. Xia, AIChE J. 2020, 66:e16858, DOI: 10.1002/aic.16858 ; Efficient adsorptive separation of propene over propane through a pillar-layer cobalt-based metal–organic framework
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