NH-MIL-101(Al)
| 【Numbering】BK2021012520 | 【CAS】1404201-64-4 | ||
| 【Item No.】 | 【specification】 | ||
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Other name: NA
CAS: 1404201-64-4
Structure information
Unit molecular formula C24N3O15Al3Cl Unit molecular weight 960.45626
Coordination metal Al ligand 2-aminoterephthalic acid (CAS: 10312-55-7)
Pore size Window: 1.2-1.6nm; Pore size: 2.9-3.4nm Pore volume ~1.0 cm3/g
Specific surface BET specific surface 2400-2800 m2/g
Analog structure
Product traits
Product appearance: light yellow powder
Particle size
Agglomeration of small amorphous nanoparticles
stability
1) NH2-MIL-101(Al) is relatively stable and can be stable for several weeks in the air. Thermal decomposition temperature>300℃.
2) Stable for several days in aqueous solution (PH 1-10)
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the oven at 80 degrees (vacuum) for 10 hours before use
Other features
NA
Application field
1) Gas storage materials and adsorption materials
2) Containing Al metal, it can be used as Lewis acid catalyst for catalytic reaction
Characterization map
references
1) Serra-Crespo, Pablo; Ramos-Fernandez, Enrique V.; Gascon, Jorge; Kapteijn, Freek; Chem. Mater. 2011, 23, 10, 2565-2572, DOI: 10.1021/cm103644b; Synthesis and Characterization of an Amino Functionalized MIL-101(Al): Separation and Catalytic Properties
2) Choluj, Artur; Nikishkin, Nicolai I.; Chmielewski, Michal J.; Chem. Commun., 2017,53, 10196-10199; DOI: 10.1039/C7CC06054H; Facile post-synthetic deamination of MOFs and the synthesis of the missing parent compound of the MIL-101 family
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