ZIF-7
| 【Numbering】BK2021012314 | 【CAS】909531-29-9 | ||
| 【Item No.】 | 【specification】 | ||
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Other names: 1H-Benzimidazole, zinc salt
CAS: 909531-29-9
Structure information
Unit molecular formula C7H6N2.Zn.H2O Unit molecular weight 201.54122
Coordination metal Zn ligand Benzimidazole (CAS: 51-17-2)
Aperture 0.43nm (Aperture: 0.24nm) Pore volume 0.18g/cm3
No N2 adsorption on specific surface, CO2 adsorption see the following figure
Analog structure
stability
1) Stable in the air, stable for several days in an aqueous solution, decomposed in an acidic solution
2) Moisture molecules in the structure will lose water at 130°C under heating, and the remaining skeleton structure will gradually decompose after it exceeds 450°C
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) If activation is required, activate in a 70 degree (vacuum) oven for 2 hours
Other features
Fluorescence: NA
Application field
1) ZIF-7 can be applied to the adsorption and separation of hydrogen and the adsorption and separation of ethane/ethylene
2) ZIF-7 has a high carbon content and can be carbonized at a high temperature to obtain a porous carbon material with a certain morphology for gas adsorption
Characterization map
references
1) Park, Kyo Sung; Ni, Zheng; Cote, Adrien P.; Choi, Jae Yong; Huang, Rudan; Uribe-Romo, Fernando J.; Chae, Hee K.; O'Keeffe, Michael; Yaghi, Omar M .; Proc. Natl. Acad. Sci. USA, 2006, 103, 10186-10191, DOI: 10.1073/pnas.0602439103; Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
2) Peng, Yuan; Li, Yanshuo; Ban, Yujie; Jin, Hua; Jiao, Wenmei; Liu, Xinlei; Yang, Weishen; Science 2014, 346(6215), 1356-1359, DOI: 10.1126/science.1254227; Metal-organic framework nanosheets as building blocks for molecular sieving membranes
3) Zhang, Peng; Sun, Fang; Xiang, Zhonghua; Shen, Zhigang; Yun, Jimmy; Cao, Dapeng; Energy & Environmental Sci. 2014, 7(1), 442-450, DOI:10.1039/C3EE42799D; ZIF- derived in situ nitrogen-doped porous carbons as efficient metal-free electrocatalysts for oxygen reduction reaction
4) Li, Yan-Shuo; Liang, Fang-Yi; Bux, Helge; Feldhoff, Armin; Yang, Wei-Shen; Caro, Juergen; Angew. Chem., Int. Ed. 2010, 49(3), 548- 551, DOI: 10.1002/anie.200905645; Molecular Sieve Membrane: Supported Metal-Organic Framework with High Hydrogen Selectivity
| Warm tips: Suzhou Beike nano products are only used for scientific research, not for human body,different batches of products have different specifications and performance |
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| Warm tips: Suzhou Beike nano products are only used for scientific research, not for human body,different batches of products have different specifications and performance.The website pictures are from the Internet. The pictures are for reference only. Please take the real object as the standard. In case of infringement, please contact us to delete them immediately. |
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