UiO-66(Zr)
| 【Numbering】BK2021012301 | 【CAS】1072413-89-8 | ||
| 【Item No.】BK2021012301-01 | 【specification】 | ||
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Other name: UIO-66-BDC
CAS: 1072413-89-8
Structure information
Unit molecular formula C48H24O32Zr6 Unit molecular weight 1660.03
Coordination metal Zr ligand Terephthalic acid (CAS: 100-21-0)
Pore diameter 0.8nm, 1.1nm Pore volume 0.5 cm3/g
Specific surface BET specific surface 1000 m2/g; BET can be increased to 1500-2000 m2/g after adding regulators
Analog structure
Product traits
Product appearance white powder
White Powder
Particle size 50-100nm; 100-200nm; 300-600nm
stability
1) UIO-66 is very stable, stable in aqueous solution and acidic conditions. UIO-66 is one of the MOFs with the best time stability and can be stored stably for a long time.
2) High thermal stability, thermal decomposition temperature greater than 400℃
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the oven at 150 degrees (vacuum) for 3 hours before use
Other features
Fluorescence: NA
Application field
1) Gas storage materials and adsorption materials
2) The rigid structure of UIO-66 is a good catalyst carrier
Characterization map
references
1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
2) S. J. Garibaya, S. M. Cohen, Chem. Commun., 2010,46, 7700-7702, DOI: 10.1039/C0CC02990D ; Isoreticular synthesis and modification of frameworks with the UiO-66 topology
3) P.Yang, F. Mao, Y. Li, Q. Zhuang, J. Gu, Chem. Eur. J. 2018, 24, 2962-2970, DOI : 10.1002/chem.201705020 ; Hierarchical Porous Zr‐Based MOFs Synthesized by a Facile Monocarboxylic Acid Etching Strategy
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